IR-Spektren einiger wasserfreien fluoro-aluminate,-gallate und -indate
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Auteurs : RBID : ISTEX:706_1971_Article_BF01167273.pdfAbstract
IR spectra of several hexa-, penta-and tetra-fluoro-metal-lates of aluminium, gallium and indium with several univalent cations together with hydrazinium(+1 and+2) were recorded from 4000 to 59 cm−1. Site group and factor group vibrational analysis was performed for the compounds with known structures. Complete agreement between theory and experiment was found only in the case of tetragonal tetrafluorometallates. No splittings of the valence and deformation modes were observed with hexafluorometallates even in the caseof low symmetry. Splitting is characteristic for penta-and tetrafluoro compounds. In the case of hydrazinium fluorometallates octa-hedral coordination was additionaly proved on the basis of position of absorption bands. Weak hydrogen bonds were used for the explanation of the spectra of ammonium ion in the corresponding compounds.
DOI: 10.1007/BF01167273
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<record><TEI><teiHeader><fileDesc><titleStmt><title>IR-Spektren einiger wasserfreien fluoro-aluminate,-gallate und -indate</title><author><name>Peter Bukovee</name><affiliation wicri:level="1"><mods:affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</mods:affiliation><country xml:lang="fr">Slovénie</country><wicri:regionArea>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana</wicri:regionArea><wicri:noRegion>Ljubljana</wicri:noRegion></affiliation></author><author><name>Boris Orel</name><affiliation wicri:level="1"><mods:affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</mods:affiliation><country xml:lang="fr">Slovénie</country><wicri:regionArea>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana</wicri:regionArea><wicri:noRegion>Ljubljana</wicri:noRegion></affiliation></author><author><name>Jože Siftar</name><affiliation wicri:level="1"><mods:affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</mods:affiliation><country xml:lang="fr">Slovénie</country><wicri:regionArea>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana</wicri:regionArea><wicri:noRegion>Ljubljana</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:706_1971_Article_BF01167273.pdf</idno><date when="1971">1971</date><idno type="doi">10.1007/BF01167273</idno><idno type="wicri:Area/Main/Corpus">000543</idno><idno type="wicri:Area/Main/Curation">000543</idno><idno type="wicri:Area/Main/Exploration">000B27</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">IR spectra of several hexa-, penta-and tetra-fluoro-metal-lates of aluminium, gallium and indium with several univalent cations together with hydrazinium(+1 and+2) were recorded from 4000 to 59 cm−1. Site group and factor group vibrational analysis was performed for the compounds with known structures. Complete agreement between theory and experiment was found only in the case of tetragonal tetrafluorometallates. No splittings of the valence and deformation modes were observed with hexafluorometallates even in the caseof low symmetry. Splitting is characteristic for penta-and tetrafluoro compounds. In the case of hydrazinium fluorometallates octa-hedral coordination was additionaly proved on the basis of position of absorption bands. Weak hydrogen bonds were used for the explanation of the spectra of ammonium ion in the corresponding compounds.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="5e593c771fbdf25f1472e2c3af3337b9665f66ac"><titleInfo lang="ger"><title>IR-Spektren einiger wasserfreien fluoro-aluminate,-gallate und -indate</title><subTitle>Untersuchungen über Fluoro-metallate(III), 3. Mitt.</subTitle></titleInfo><name type="personal"><namePart type="given">Peter</namePart><namePart type="family">Bukovee</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</affiliation></name><name type="personal"><namePart type="given">Boris</namePart><namePart type="family">Orel</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</affiliation></name><name type="personal"><namePart type="given">Jože</namePart><namePart type="family">Siftar</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratorium für anorganische Chemie der Universität Ljubljana und Institut “Jožef Stefan”, Ljubljana, (Jugoslawien)</affiliation></name><typeOfResource>text</typeOfResource><genre>Anorganische, Struktur- und Physikalische Chemie</genre><genre>Original Paper</genre><originInfo><publisher>Springer-Verlag, Vienna</publisher><dateCreated encoding="w3cdtf">1971-01-18</dateCreated><dateValid encoding="w3cdtf">2005-01-30</dateValid><copyrightDate encoding="w3cdtf">1971</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">ger</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">IR spectra of several hexa-, penta-and tetra-fluoro-metal-lates of aluminium, gallium and indium with several univalent cations together with hydrazinium(+1 and+2) were recorded from 4000 to 59 cm−1. Site group and factor group vibrational analysis was performed for the compounds with known structures. Complete agreement between theory and experiment was found only in the case of tetragonal tetrafluorometallates. No splittings of the valence and deformation modes were observed with hexafluorometallates even in the caseof low symmetry. Splitting is characteristic for penta-and tetrafluoro compounds. In the case of hydrazinium fluorometallates octa-hedral coordination was additionaly proved on the basis of position of absorption bands. Weak hydrogen bonds were used for the explanation of the spectra of ammonium ion in the corresponding compounds.</abstract><abstract lang="ger">Hexa-, Penta-und Tetra-fluorometallate von aluminium, Gallium, Indium, einigen einwertigen Ionen und von Hydrazinium(1+ und2+) wurden im Spektralbereich von 4000 bis 59 cm−1 untersucht. Für die Verbindungen mit bekannten Strukturen wurden die Faktorgruppenanalyse und Vibrations-analyse auf Grund der Lagesymmetrie ausgeführt. Vollkommene Übereinstimmung zwischen den theoretischen und experimentellen Daten ergibt sich nur bei den tetragonalen Tetrafluorometallaten. Bei Hexafluorometallaten erscheint bei niedrigeren Symmetrien auch keine Aufspaltung der Valenz-und Deformations-Banden. Eine Aufspaltung ist aber charakteristisch für die Penta-und Tetrafluorometallate. Auf Grund der Lage der Banden wird zusätzlich die oktaedrische Koordination in den Hydraziniumfluorometallaten bewiesen. Mit der schwachen Wasserstoffbindung sind die IR-Spektren der NH4+-Ionen in deren Verbindungen erklärbar.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>Monatshefte für Chemie</title></titleInfo><titleInfo><title>Monatshefte für Chemie / Chemical Monthly</title><partNumber>Year: 1971</partNumber><partNumber>Volume: 102</partNumber><partNumber>Number: 3</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1971-05-01</dateIssued><copyrightDate encoding="w3cdtf">1971</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Chemistry/Food Science, general</topic><topic>Analytical Chemistry</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Theoretical and Computational Chemistry</topic></subject><identifier type="issn">0026-9247</identifier><identifier type="issn">Electronic: 1434-4475</identifier><identifier type="matrixNumber">706</identifier><identifier type="local">IssueArticleCount: 36</identifier><recordInfo><recordOrigin>Springer-Verlag, 1971</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF01167273</identifier><identifier type="matrixNumber">Art32</identifier><identifier type="local">BF01167273</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>885</start><end>895</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1971</recordOrigin><recordIdentifier>706_1971_Article_BF01167273.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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